Electricity will Rescue the Steel Industry from Dirt

According to Mining News Pro –  When you climb up a set of stairs to look over Boston Metal’s newest project, it becomes clear just how big a job it is to cut steel’s climate impact.

The impressive new installation is a pilot reactor that the startup will use to make emissions-free steel. It’s about the size of a school bus, set down into the floor of the research facility; the stairs, with freshly painted yellow railings, lead to the top. But in the steel industry, which produces nearly 2 billion tons per year, this setup’s potential output is a drop in the bucket.

Industrial steelmaking spits out about two tons of carbon dioxide emissions for every ton of steel produced—adding up to nearly 10% of such emissions worldwide. The global steel market is expected to grow about 30% by 2050, the date by which some of the largest steelmakers have pledged to reach net-zero emissions. Unless major changes come to the industry, and fast, that goal might be out of reach.

Boston Metal’s new reactor, recently installed at its headquarters just north of Boston, is a significant step on the company’s journey to going commercial. Since its founding in 2013, the startup has developed a process to make green steel, working out the details in smaller vessels. The new reactor, along with a coming fundraising round, represents the next leap for the company as it tries to scale up.

If Boston Metal can indeed scale its clean production process and access enough renewable electricity to run it, the company could help solve one of the world’s toughest challenges in controlling carbon emissions.

A new approach

Steel is used in everything from cars to buildings to wind turbines, but decarbonizing the industry isn’t glamorous. “People don’t pay too much attention to the industrials,” says Tadeu Carneiro, Boston Metal’s CEO. “It’s a very conservative industry, and it’s difficult to abate.”

Fossil fuels are essential to today’s steel production. Most steelmaking starts in a blast furnace, where a coal-derived material called coke, which is almost pure carbon, reacts with iron ore, a mixture of iron oxides and other minerals. The reaction pulls out the oxygen, leaving behind liquid iron. The carbon and oxygen are then released together as carbon dioxide.

Boston Metal’s solution is an entirely new approach, called molten oxide electrolysis (MOE). Instead of using carbon to remove oxygen, the process relies on electricity, which runs through a cell filled with a mixture of dissolved iron oxides along with other oxides and materials. The electricity heats the cell up to about 1,600 °C (nearly 3,000 °F), melting everything into a hot oxide soup.

In addition to heating things up, electricity drives the oxygen-removing chemical reactions. Molten iron gathers at the bottom of the reactor, and oxygen gas is emitted instead of carbon dioxide.

Because the impurities largely stay out of the reaction, the MOE process can handle low-quality iron ore, which could be a major benefit of the technology, Carneiro says.

Sizing up

Boston Metal’s steelmaking process was developed by MIT materials researchers Donald Sadoway and Antoine Allanore in the mid-2000s. Research progressed in small reactors about the size of a coffee cup; these lab versions now produce a peanut-size amount of iron within a couple of days.

A major challenge so far in transitioning to larger reactors has to do with the stability of the inert anode, a metal piece made from a mixture of steel and chromium, says Stephan Broek, Boston Metal’s senior vice president of technology. If the reactor runs as it should, the anode doesn’t participate in the reaction: it just provides a way for electricity to move through the cell. But the anode tends to degrade quickly if the balance between conditions like current distribution and electrolyte chemistry isn’t quite right.

This and other challenges could get even more serious with the new pilot reactor, which is about a thousand times bigger than the research version.

The new reactor will run a current of up to 25,000 amperes (a typical home uses between 100 and 200). It’s outfitted with multiple anodes and all the trappings of the eventual first industrial-size cell, which will be about 10 times bigger still.

Construction on the pilot reactor is almost finished, and tests are slated to begin in August. First, it will be used with carbon anodes to produce ferroalloys, high-value metals that can be produced in an electrolysis process similar to the one used to make steel. After the reactor is tried out for that product, the team plans to convert it for use in steelmaking sometime early next year, Broek says.